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  2. Magnetic inequivalence - Wikipedia

    en.wikipedia.org/wiki/Magnetic_inequivalence

    A classic example is the 1 H-NMR spectrum of 1,1-difluoroethylene. [5] The single 1 H-NMR signal is made complex by the 2 J H-H and two different 3 J H-F splittings. The 19 F-NMR spectrum will look identical. The other two difluoroethylene isomers give similarly complex spectra. [6]

  3. Proton nuclear magnetic resonance - Wikipedia

    en.wikipedia.org/wiki/Proton_nuclear_magnetic...

    Proton nuclear magnetic resonance (proton NMR, hydrogen-1 NMR, or 1 H NMR) is the application of nuclear magnetic resonance in NMR spectroscopy with respect to hydrogen-1 nuclei within the molecules of a substance, in order to determine the structure of its molecules. [1]

  4. Hexamethylbenzene - Wikipedia

    en.wikipedia.org/wiki/Hexamethylbenzene

    Hexamethylbenzene, also known as mellitene, is a hydrocarbon with the molecular formula C 12 H 18 and the condensed structural formula C 6 (CH 3) 6.It is an aromatic compound and a derivative of benzene, where benzene's six hydrogen atoms have each been replaced by a methyl group.

  5. Triple-resonance nuclear magnetic resonance spectroscopy

    en.wikipedia.org/wiki/Triple-resonance_nuclear...

    Triple resonance experiments are a set of multi-dimensional nuclear magnetic resonance spectroscopy (NMR) experiments that link three types of atomic nuclei, most typically consisting of 1 H, 15 N and 13 C. These experiments are often used to assign specific resonance signals to specific atoms in an isotopically-enriched protein.

  6. Nuclear magnetic resonance spectroscopy - Wikipedia

    en.wikipedia.org/wiki/Nuclear_magnetic_resonance...

    Example 1 H NMR spectrum (1-dimensional) of ethanol plotted as signal intensity vs. chemical shift. There are three different types of H atoms in ethanol regarding NMR: the hydrogen (H) on the −OH group is not coupling with the other H atoms and appears as a singlet, but the CH 3 − and the −CH 2 − hydrogens are coupling with each other ...

  7. Metallabenzene - Wikipedia

    en.wikipedia.org/wiki/Metallabenzene

    The first reported stable metallabenzene was the osmabenzene Os(C 5 H 4 S)CO(PPh 3) 2. [4] [2] Characteristic of other metallaarenes, the Os-C bonds are about 0.6 Å longer than the C-C bonds (in benzene these are 1.39 Å), resulting in a distortion of the hexagonal ring. 1 H NMR signals for the ring protons are downfield, consistent with aromatic

  8. 1,2,4,5-Tetrachloro-3-nitrobenzene - Wikipedia

    en.wikipedia.org/wiki/1,2,4,5-tetrachloro-3...

    It is a colorless solid. A related isomer is 1,2,3,4-tetrachloro-5-nitrobenzene. It is used as a standard for quantitative analysis by nuclear magnetic resonance. [4] [5] 1,2,4,5-Tetrachloro-3-nitrobenzene is also a fungicide used to prevent dry rot and sprouting on potatoes during storage. [6] [7]

  9. Mesitylene - Wikipedia

    en.wikipedia.org/wiki/Mesitylene

    Mesitylene or 1,3,5-trimethylbenzene is a derivative of benzene with three methyl substituents positioned symmetrically around the ring. The other two isomeric trimethylbenzenes are 1,2,4-trimethylbenzene (pseudocumene) and 1,2,3-trimethylbenzene (hemimellitene).