Search results
Results from the WOW.Com Content Network
These processes are called Umklapp scattering and change the total phonon momentum. Umklapp scattering is the dominant process for electrical resistivity at low temperatures for low defect crystals [1] (as opposed to phonon-electron scattering, which dominates at high temperatures, and high-defect lattices which lead to scattering at any ...
A phonon is a collective excitation in a periodic, elastic arrangement of atoms or molecules in condensed matter, specifically in solids and some liquids.A type of quasiparticle in physics, [1] a phonon is an excited state in the quantum mechanical quantization of the modes of vibrations for elastic structures of interacting particles.
where is the characteristic length of the system and represents the fraction of specularly scattered phonons. The p {\displaystyle p} parameter is not easily calculated for an arbitrary surface. For a surface characterized by a root-mean-square roughness η {\displaystyle \eta } , a wavelength-dependent value for p {\displaystyle p} can be ...
The Kiliani–Fischer synthesis, named for German chemists Heinrich Kiliani and Emil Fischer, is a method for synthesizing monosaccharides.It proceeds via synthesis and hydrolysis of a cyanohydrin, followed by reduction of the intermediate acid to the aldehyde, thus elongating the carbon chain of an aldose by one carbon atom while preserving stereochemistry on all the previously present chiral ...
A theory that is asymmetric with respect to chiralities is called a chiral theory, while a non-chiral (i.e., parity-symmetric) theory is sometimes called a vector theory. Many pieces of the Standard Model of physics are non-chiral, which is traceable to anomaly cancellation in chiral theories.
Chiral phosphine ligands, especially C 2-symmetric ligands, are the source of chirality in most asymmetric hydrogenation catalysts. Of these the BINAP ligand is well-known, as a result of its Nobel Prize-winning application in the Noyori asymmetric hydrogenation. [3] Chiral phosphine ligands can be generally classified as mono- or bidentate ...
Acoustic metamaterials or phononic crystals can be understood as the acoustic analog of photonic crystals: instead of electromagnetic waves (photons) propagating through a material with a periodically modified optical refractive index (resulting in a modified speed of light), the phononic crystal comprises pressure waves (phonons) propagating ...
The term "chiral" in general is used to describe the object that is non-superposable on its mirror image. [18] In chemistry, chirality usually refers to molecules. Two mirror images of a chiral molecule are called enantiomers or optical isomers. Pairs of enantiomers are often designated as "right-", "left-handed" or, if they have no bias ...