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Two crystalline forms are known, both being very similar to the corresponding potassium sulfate. Orthorhombic β-K 2 CrO 4 is the common form, but it converts to an α-form above 66 °C. [1] These structures are complex, although the chromate ion adopts the typical tetrahedral geometry. [2]
For example, at 2,200 °C (2,470 K; 3,990 °F) about three percent of all H 2 O are dissociated into various combinations of hydrogen and oxygen atoms, mostly H, H 2, O, O 2, and OH. Other reaction products like H 2 O 2 or HO 2 remain minor. At the very high temperature of 3,000 °C (3,270 K; 5,430 °F) more than half of the water molecules are ...
2Cr 2 O 3 + 4 Na 2 CO 3 + 3 O 2 → 4 Na 2 CrO 4 + 4 CO 2 This process converts the chromium into a water-extractable form, leaving behind iron oxides. Typically calcium carbonate is included in the mixture to improve oxygen access and to keep silicon and aluminium impurities in an insoluble form.
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2 CrCl 3 + Zn → 2 CrCl 2 + ZnCl 2. CrCl 2 can also be prepared by treating a solution of chromium(II) acetate with hydrogen chloride: [6] Cr 2 (OAc) 4 + 4 HCl → 2 CrCl 2 + 4 AcOH. Treatment of chromium powder with concentrated hydrochloric acid gives a blue hydrated chromium(II) chloride, which can be converted to a related acetonitrile ...
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The anhydrous form of chromium(II) acetate, and also related chromium(II) carboxylates, can be prepared from chromocene: 4 RCO 2 H + 2 Cr(C 5 H 5) 2 → Cr 2 (O 2 CR) 4 + 4 C 5 H 6. This method provides anhydrous derivatives in a straightforward manner. [8] Because it is so easily prepared, Cr 2 (OAc) 4 (H 2 O) 2 is a