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Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
This rate can be quantified through the calculation and application of mass transfer coefficients for an overall process. These mass transfer coefficients are typically published in terms of dimensionless numbers, often including Péclet numbers, Reynolds numbers, Sherwood numbers, and Schmidt numbers, among others. [2] [3] [4]
Here, is the overall mass transfer coefficient, which could be determined by empirical correlations, is the surface area for mass transfer (particularly relevant in membrane-based separations), and ˙ is the mass flowrate of bulk fluid (e.g., mass flowrate of air in an application where water vapor is being separated from the air mixture). At ...
There are some notable similarities in equations for momentum, energy, and mass transfer [7] which can all be transported by diffusion, as illustrated by the following examples: Mass: the spreading and dissipation of odors in air is an example of mass diffusion. Energy: the conduction of heat in a solid material is an example of heat diffusion.
D is mass diffusivity (m 2 s −1) h is the convective mass transfer film coefficient (m s −1) Using dimensional analysis, it can also be further defined as a function of the Reynolds and Schmidt numbers: = (,) For example, for a single sphere it can be expressed as [citation needed]:
This equation permits the prediction of an unknown transfer coefficient when one of the other coefficients is known. The analogy is valid for fully developed turbulent flow in conduits with Re > 10000, 0.7 < Pr < 160, and tubes where L/d > 60 (the same constraints as the Sieder–Tate correlation). The wider range of data can be correlated by ...
The overall heat transfer coefficient takes into account the individual heat transfer coefficients of each stream and the resistance of the pipe material. It can be calculated as the reciprocal of the sum of a series of thermal resistances (but more complex relationships exist, for example when heat transfer takes place by different routes in ...
In convective heat transfer, the Churchill–Bernstein equation is used to estimate the surface averaged Nusselt number for a cylinder in cross flow at various velocities. [1] The need for the equation arises from the inability to solve the Navier–Stokes equations in the turbulent flow regime, even for a Newtonian fluid .