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p-bromochlorobenzene para-bromochlorobenzene Systematic name: 1-bromo-2-chlorobenzene 1-bromo-3-chlorobenzene 1-bromo-4-chlorobenzene Molecular formula: BrC 6 H 4 Cl
Grignard reagents do not typically couple with chlorinated arenes. This low reactivity is the basis for chemoselectivity for nickel insertion into the C–Br bond of bromochlorobenzene using a NiCl 2-based catalyst. [21] NiCl 2 catalyzed Kumada coupling shows haloselectivity on bromochlorobenzene.
Bromobenzene is prepared by the action of bromine on benzene in the presence of Lewis acid catalysts such as aluminium chloride or ferric bromide. [3]Bromobenzene is used to introduce a phenyl group into other compounds.
4-Fluorobromobenzene is synthesized via bromination of fluorobenzene in the presence of a Lewis acid catalyst such as iron(III) bromide or aluminium tribromide. [2]4-Bromofluorobenzene is regarded by the Toxic Substances Control Act as a high production volume chemical, that is, a chemical that 1 million pounds (about 500 tonnes) per year is either produced in or imported to the United States.
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Monobromotoluene isomers [1] [2] [3]; Common name Structure Systematic name: 1-bromo-2-methylbenzene 1-bromo-3-methylbenzene 1-bromo-4-methylbenzene Molecular formula
Benzyl bromide is used in organic synthesis for the introduction of the benzyl groups when the less expensive benzyl chloride is insufficiently reactive. [6] [7] Benzylations are often achieved in the presence of catalytic amounts of sodium iodide, which generates the more reactive benzyl iodide in situ. [3]