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Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
Calcium hydroxide is moderately soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
Ca(OH) 2 or CaO · H 2 O: Calcium hydroxide (portlandite) C-S-H: 0.6–2.0 CaO · SiO 2 · 0.9–2.5 H 2 O, with variable composition within this range, and often also incorporating partial substitution of Al for Si: Calcium silicate hydrate: C-A-H: Phase more complex than C-S-H: Calcium aluminate hydrate C-A-S-H: This is even more complex than ...
Calcium bicarbonate, also called calcium hydrogencarbonate, has the chemical formula Ca(HCO 3) 2. The term does not refer to a known solid compound; it exists only in aqueous solution containing calcium (Ca 2+), bicarbonate (HCO − 3), and carbonate (CO 2− 3) ions, together with dissolved carbon dioxide (CO 2).
CaO + H 2 O → Ca(OH) 2 Ca(OH) 2 + CO 2 → CaCO 3 + H 2 O. In a laboratory, calcium carbonate can easily be crystallized from calcium chloride (CaCl 2), by placing an aqueous solution of CaCl 2 in a desiccator alongside ammonium carbonate [NH 4] 2 CO 3. [10] In the desiccator, ammonium carbonate is exposed to air and decomposes into ammonia ...
The temperature can reach up to some 300 °C (572 °F). The major use of quicklime is in the basic oxygen steelmaking (BOS) process. Its usage varies from about 30 to 50 kilograms (65–110 lb) per ton of steel. The quicklime neutralizes the acidic oxides, SiO 2, Al 2 O 3, and Fe 2 O 3, to produce a basic molten slag. [10]
Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO 2. It is the peroxide (O 2 2−) salt of Ca 2+. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in water. [3]