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The solubility of gas obeys Henry's law, that is, the amount of a dissolved gas in a liquid is proportional to its partial pressure. Therefore, placing a solution under reduced pressure makes the dissolved gas less soluble. Sonication and stirring under reduced pressure can usually enhance the efficiency.
Depressurisation causes inert gases, which were dissolved under higher pressure, to come out of physical solution and form gas bubbles within the body. These bubbles produce the symptoms of decompression sickness. [17] [52] Bubbles may form whenever the body experiences a reduction in pressure, but not all bubbles result in DCS. [53]
However, for aqueous solutions, the Henry's law solubility constant for many species goes through a minimum. For most permanent gases, the minimum is below 120 °C. Often, the smaller the gas molecule (and the lower the gas solubility in water), the lower the temperature of the maximum of the Henry's law constant.
Measurements of primary productivity in the ocean can be made using this ratio. The concentration of oxygen dissolved in seawater varies according to biological processes (photosynthesis and respiration) as well as physical processes (air-sea gas exchange, temperature and pressure changes, lateral mixing and vertical diffusion).
Once dissolved, distribution of the dissolved gas is by perfusion, where the solvent (blood) is circulated around the diver's body, and by diffusion, where dissolved gas can spread to local regions of lower concentration when there is no bulk flow of the solvent. Given sufficient time at a specific partial pressure in the breathing gas, the ...
Inert gas such as nitrogen or helium continues to be taken up until the gas dissolved in the diver is in a state of equilibrium with the breathing gas in the diver's lungs, at which point the diver is saturated for that depth and breathing mixture, or the depth, and therefore the pressure, is changed, or the partial pressures of the gases are ...
Marine chemistry, also known as ocean chemistry or chemical oceanography, is the study of the chemical composition and processes of the world’s oceans, including the interactions between seawater, the atmosphere, the seafloor, and marine organisms. [2]
Water becomes less dense as its temperature increases and the distance between its molecules expands, but more dense as the salinity increases, since there is a larger mass of salts dissolved within that water. [15] Further, while fresh water is at its most dense at 4 °C, seawater only gets denser as it cools, up until it reaches the freezing ...