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where A is the reactant and S is an adsorption site on the surface and the respective rate constants for the adsorption, desorption and reaction are k 1, k −1 and k 2, then the global reaction rate is: = = where: r is the rate, mol·m −2 ·s −1
Iron rusting has a low reaction rate. This process is slow. Wood combustion has a high reaction rate. This process is fast. The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. [1]
The lateral surface area of a right circular cone is = where is the radius of the circle at the bottom of the cone and is the slant height of the cone. [4] The surface area of the bottom circle of a cone is the same as for any circle, . Thus, the total surface area of a right circular cone can be expressed as each of the following:
The constant is the reaction rate constant or rate coefficient and at very few places velocity constant or specific rate of reaction. Its value may depend on conditions such as temperature, ionic strength, surface area of an adsorbent , or light irradiation .
A sphere of radius r has surface area 4πr 2.. The surface area (symbol A) of a solid object is a measure of the total area that the surface of the object occupies. [1] The mathematical definition of surface area in the presence of curved surfaces is considerably more involved than the definition of arc length of one-dimensional curves, or of the surface area for polyhedra (i.e., objects with ...
where k f and k b are the reaction rate constants, with units of frequency (1/time) and c o and c r are the surface concentrations (mol/area) of the oxidized and reduced molecules, respectively (written as c o (0,t) and c r (0,t) in the previous section). The net rate of reaction v and net current density j are then: [Note 2]
Area#Area formulas – Size of a two-dimensional surface; Perimeter#Formulas – Path that surrounds an area; List of second moments of area; List of surface-area-to-volume ratios – Surface area per unit volume; List of surface area formulas – Measure of a two-dimensional surface; List of trigonometric identities
The area around a molecule A in which it can collide with an approaching B molecule is called the cross section (σ AB) of the reaction and is, in simplified terms, the area corresponding to a circle whose radius is the sum of the radii of both reacting molecules, which are supposed to be spherical.