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The sublimation that occurs at the solid-gas boundary (critical sublimation point) (corresponding to boiling in vaporization) may be called rapid sublimation, and the substance sublimes rapidly. The words "gradual" and "rapid" have acquired special meanings in this context and no longer describe the rate of sublimation. [citation needed]
In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Gas HCN 130.5 Hydrogen bromide: Liquid HBr −36.3 Hydrogen chloride: Gas HCl −92.30 Hydrogen chloride: Aqueous HCl −167.2 Hydrogen fluoride: Gas HF −273.3 Hydrogen iodide: Gas HI 26.5 Iodine: Solid I 2: 0 Iodine: Gas I 2: 62.438 Iodine: Aqueous I 2: 23 Iodide ion Aqueous I −: −55 Iron: Solid Fe 0 Iron carbide Solid Fe 3 C 5.4 Iron(II ...
This includes the latent heat of fusion (solid to liquid), the latent heat of vaporization (liquid to gas) and the latent heat of sublimation (solid to gas). [1] [2] The term was introduced around 1762 by Scottish chemist Joseph Black.
The reaction of molybdenum dioxide with the transporting agent iodine is an exothermic process, thus the MoO 2 migrates from the cooler end (700 °C) to the hotter end (900 °C): MoO 2 + I 2 ⇌ MoO 2 I 2 ΔH rxn < 0 (exothermic) Using 10 milligrams of iodine for 4 grams of the solid, the process requires several days.
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Phase transitions commonly refer to when a substance transforms between one of the four states of matter to another. At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identical free energies and therefore are equally likely to exist.