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Lime softening (also known as lime buttering, lime-soda treatment, or Clark's process) [1] is a type of water treatment used for water softening, which uses the addition of limewater (calcium hydroxide) to remove hardness (deposits of calcium and magnesium salts) by precipitation.
Calcium hydroxide is modestly soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes
As more aluminum sulfate is added, water pH decreases. At higher pH, the soluble species Al(OH) 4 − is present. In neutral pH ranges (6–8), the insoluble aluminum hydroxide (Al(OH) 3) occurs. As pH decreases further, the Al(III) ion remains present. [2] Maintaining optimal pH is important for the removal of phosphorus from water.
The percentage of the weight of CuSO 4 to the weight of water employed determines the concentration of the mixture. Thus a 1% Bordeaux mixture, which is typical, would have the formula 1:1:100, with the first "1" representing 1 kg CuSO 4 (pentahydrated), the second representing 1 kg hydrated lime, and the 100 representing 100 litres (100 kg) water.
Lime sulfur reacts with strong acids (including stomach acid) to produce highly toxic hydrogen sulfide (rotten egg gas) and indeed usually has a distinct "rotten egg" odor to it. Lime sulfur is not flammable but can release highly irritating sulfur dioxide gas when in a fire. Safety goggles and impervious gloves must be worn while handling lime ...
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An example batch calculation may be demonstrated here. The desired glass composition in wt% is: 67 SiO 2, 12 Na 2 O, 10 CaO, 5 Al 2 O 3, 1 K 2 O, 2 MgO, 3 B 2 O 3, and as raw materials are used sand, trona, lime, albite, orthoclase, dolomite, and borax. The formulas and molar masses of the glass and batch components are listed in the following ...