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An overview of absorption of electromagnetic radiation. This example shows the general principle using visible light as a specific example. A white light source—emitting light of multiple wavelengths—is focused on a sample (the pairs of complementary colors are indicated by the yellow dotted lines).
Beer's law states that a beam of visible light passing through a chemical solution of fixed geometry experiences absorption proportional to the solute concentration. Other applications appear in physical optics , where it quantifies astronomical extinction and the absorption of photons , neutrons , or rarefied gases .
Upon striking the sample, photons that match the energy gap of the molecules present (green light in this example) are absorbed in order to excite the molecule. Other photons transmit unaffected and, if the radiation is in the visible region (400–700 nm), the sample color is the complementary color of the absorbed light.
Extinction coefficient refers to several different measures of the absorption of light in a medium: Attenuation coefficient, sometimes called "extinction coefficient" in meteorology or climatology Mass extinction coefficient, how strongly a substance absorbs light at a given wavelength, per mass density
The absorption coefficient is fundamentally the product of a quantity of absorbers per unit volume, [cm −3], times an efficiency of absorption (area/absorber, [cm 2]). Several sources [ 2 ] [ 12 ] [ 3 ] replace nσ λ with k λ r , where k λ is the absorption coefficient per unit density and r is the density of the gas.
In atomic, molecular, and optical physics, the Einstein coefficients are quantities describing the probability of absorption or emission of a photon by an atom or molecule. [1] The Einstein A coefficients are related to the rate of spontaneous emission of light, and the Einstein B coefficients are related to the absorption and stimulated ...
For example, white paint is quoted as having an absorptivity of 0.16, while having an emissivity of 0.93. [13] This is because the absorptivity is averaged with weighting for the solar spectrum, while the emissivity is weighted for the emission of the paint itself at normal ambient temperatures.
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
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