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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
The Bohr radius ( ) is a physical constant, approximately equal to the most probable distance between the nucleus and the electron in a hydrogen atom in its ground state. It is named after Niels Bohr, due to its role in the Bohr model of an atom. Its value is 5.291 772 105 44(82) × 10−11 m. [1][2]
This was a significant step in the development of quantum mechanics. It also described the possibility of atomic energy levels being split by a magnetic field (called the Zeeman effect). Walther Kossel worked with Bohr and Sommerfeld on the Bohr–Sommerfeld model of the atom introducing two electrons in the first shell and eight in the second. [8]
The Balmer series is characterized by the electron transitioning from n ≥ 3 to n = 2, where n refers to the radial quantum number or principal quantum number of the electron. The transitions are named sequentially by Greek letter: n = 3 to n = 2 is called H-α, 4 to 2 is H-β, 5 to 2 is H-γ, and 6 to 2 is H-δ.
The principal quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals. However, the modern theory still requires the principal quantum ...
In spectroscopy, the Rydberg constant, symbol for heavy atoms or for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first arose as an empirical fitting parameter in the Rydberg formula for the hydrogen spectral series, but Niels Bohr later ...
Matrix mechanics is a formulation of quantum mechanics created by Werner Heisenberg, Max Born, and Pascual Jordan in 1925. It was the first conceptually autonomous and logically consistent formulation of quantum mechanics. Its account of quantum jumps supplanted the Bohr model 's electron orbits.
Relativistic corrections (Dirac) to the energy levels of a hydrogen atom from Bohr's model. The fine structure correction predicts that the Lyman-alpha line (emitted in a transition from n = 2 to n = 1) must split into a doublet. The total effect can also be obtained by using the Dirac equation. In this case, the electron is treated as non ...