Search results
Results from the WOW.Com Content Network
Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i.e., work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [1]
It has been shown that at energies of the order of the Z 0 boson rest energy, m z c 2 ≈ 90 GeV, that: rather than the low-energy α ≈ 1 / 137 . [ 122 ] [ 123 ] The renormalization procedure of eliminating zero-point energy infinities allows the choice of an arbitrary energy (or distance) scale for defining α .
A thermodynamic free entropy is an entropic thermodynamic potential analogous to the free energy. Also known as a Massieu, Planck, or Massieu–Planck potentials (or functions), or (rarely) free information. In statistical mechanics, free entropies frequently appear as the logarithm of a partition function.
Total energy is the sum of rest energy = and relativistic kinetic energy: = = + Invariant mass is mass measured in a center-of-momentum frame. For bodies or systems with zero momentum, it simplifies to the mass–energy equation E 0 = m 0 c 2 {\displaystyle E_{0}=m_{0}c^{2}} , where total energy in this case is equal to rest energy.
An alternative to free-energy perturbation for computing potentials of mean force in chemical space is thermodynamic integration. Another alternative, which is probably more efficient, is the Bennett acceptance ratio method. Adaptations to FEP exist which attempt to apportion free-energy changes to subsections of the chemical structure. [5]
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.
The Helmholtz free energy is a useful quantity when studying thermodynamic transformations in which the temperature is held constant. Although the reduction in the number of variables is a useful simplification, the main advantage comes from the fact that the Helmholtz free energy is minimized at equilibrium with respect to any unconstrained ...
Mass–energy equivalence states that all objects having mass, or massive objects, have a corresponding intrinsic energy, even when they are stationary.In the rest frame of an object, where by definition it is motionless and so has no momentum, the mass and energy are equal or they differ only by a constant factor, the speed of light squared (c 2).