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This is more common in TCF bleaching sequences for two reasons: the acidic chlorine or chlorine dioxide stages tend to remove metal ions (metal ions usually being more soluble at lower pH), and TCF stages rely more heavily on oxygen-based bleaching agents, which are more susceptible to the detrimental effects of these metal ions.
Elemental chlorine free (ECF) is a technique that uses chlorine dioxide for the bleaching of wood pulp.It does not use elemental chlorine gas during the bleaching process and prevents the formation of dioxins and dioxin-like compounds, carcinogens.
The principal example is tert-butyl hypochlorite, which is a useful chlorinating agent. [3] Most hypochlorite salts are handled as aqueous solutions. Their primary applications are as bleaching, disinfection, and water treatment agents. They are also used in chemistry for chlorination and oxidation reactions.
Trichloroisocyanuric acid is an organic compound with the formula (CONCl) 3.It is used as an industrial disinfectant, bleaching agent and a reagent in organic synthesis. [1] [2] [3] This white crystalline powder, which has a strong "chlorine odour," is sometimes sold in tablet or granule form for domestic and industrial use.
[38] Most TCF pulp is produced in Sweden and Finland for sale in Germany, [36] all markets with a high level of environmental awareness. In 1999, TCF pulp represented 25% of the European market. [39] TCF bleaching, by removing chlorine from the process, reduces chlorinated organic compounds to background levels in pulp mill effluent. [40]
Percent active chlorine in these materials ranges from 20% for bleaching powder to 70% for HTH. Potassium hypochlorite, KOCl. This was the first chlorine-based bleaching agent, which became available around 1785 under the name Eau de Javel or "Javel water". It is no longer commonly used, having been superseded by the cheaper sodium analog.
It readily reacts with common wood pulp bleaching agents like ozone, peracetic acid, and chlorine dioxide. [ 2 ] [ 1 ] Consequently, research has focused on ways to break down hexenuronic acid prior to bleaching to decrease dangerous waste products and costs.
Dichloroisocyanuric acid is an oxidizer, reacting with water to form chlorine gas. [2]Although the bleaching agent in most chlorine based bleach is sodium hypochlorite, the sodium salt of dichloroisocyanuric acid, sodium dichloroisocyanurate, is the active ingredient in commercial disinfectant bacteriocides, algicides, and cleaning agents [3] such as the pulverized cleanser Comet.