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In atmospheric chemistry, NO x is shorthand for nitric oxide (NO) and nitrogen dioxide (NO 2), the nitrogen oxides that are most relevant for air pollution. [1] [2] These gases contribute to the formation of smog and acid rain, as well as affecting tropospheric ozone.
In atmospheric chemistry: NO x (or NOx) refers to the sum of NO and NO 2. [1] [2] NO y (or NOy) refers to the sum of NO x and all oxidized atmospheric odd-nitrogen species (e.g. the sum of NO x, HNO 3, HNO 2, etc.) NO z (or NOz) = NO y − NO x; Mixed Oxides of Nitrogen ("MON"): solutions of nitric oxide in dinitrogen tetroxide/nitrogen dioxide.
Ammonia flow is in general controlled based on NOx measurements taken from the gas stream or preexisting performance curves from an engine manufacturer (in the case of gas turbines and reciprocating engines). Typically, all future operating conditions must be known beforehand to properly design and tune an SCR system.
Selective non-catalytic reduction (SNCR) is a method to lessen nitrogen oxide emissions in conventional power plants that burn biomass, waste and coal.The process involves injecting either ammonia or urea into the firebox of the boiler at a location where the flue gas is between 1,400 and 2,000 °F (760 and 1,090 °C) to react with the nitrogen oxides formed in the combustion process.
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
The term NO x represents several forms of nitrogen oxides such as NO (nitric oxide), NO 2 (nitrogen dioxide) and N 2 O (nitrous oxide, also known as laughing gas). In a gasoline engine , NO is the most common form of NO x at around 93%, while NO 2 is around 5% and the rest is N 2 O.
Zel'dovich mechanism is a chemical mechanism that describes the oxidation of nitrogen and NO x formation, first proposed by the Russian physicist Yakov Borisovich Zel'dovich in 1946.
In organic chemistry, peroxyacyl nitrates (also known as Acyl peroxy nitrates, APN or PANs) are powerful respiratory and eye irritants present in photochemical smog. They are nitrates produced in the thermal equilibrium between organic peroxy radicals by the gas -phase oxidation of a variety of volatile organic compounds (VOCs), or by aldehydes ...