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Cycloalkanes and aromatic compounds can be treated as the main parent chain of the compound, in which case the positions of substituents are numbered around the ring structure. For example, the three isomers of xylene CH 3 C 6 H 4 CH 3 , commonly the ortho- , meta- , and para- forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4 ...
Cycloalkane. Ball-and-stick model of cyclobutane. In organic chemistry, the cycloalkanes (also called naphthenes, but distinct from naphthalene) are the monocyclic saturated hydrocarbons. [1] In other words, a cycloalkane consists only of hydrogen and carbon atoms arranged in a structure containing a single ring (possibly with side chains), and ...
The cyclohexanone–cyclohexanol mixture, called " KA oil ", is a raw material for adipic acid and caprolactam, precursors to nylon. Several million kilograms of cyclohexanone and cyclohexanol are produced annually. [8] It is used as a solvent in some brands of correction fluid. Cyclohexane is sometimes used as a non-polar organic solvent ...
A substitution reaction (also known as single displacement reaction or single substitution reaction) is a chemical reaction during which one functional group in a chemical compound is replaced by another functional group. [ 1 ] Substitution reactions are of prime importance in organic chemistry. Substitution reactions in organic chemistry are ...
Syn and anti addition. In organic chemistry, syn- and anti-addition are different ways in which substituent molecules can be added to an alkene (R2C=CR2) or alkyne (RC≡CR). The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction.
A value. The A-value for a methyl group is 1.74 as derived from the chemical equilibrium above. This means it costs 1.74 kcal/mol (7.3 kJ/mol) of energy to have a methyl group in the axial position compared to the equatorial position. A-values are numerical values used in the determination of the most stable orientation of atoms in a molecule ...
Heterocyclic compound. A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring (s). [1] Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of organic heterocycles. [2]
RXNO:0000006. Diels–Alder reaction, simplest example. In organic chemistry, the Diels–Alder reaction is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene derivative. It is the prototypical example of a pericyclic reaction with a concerted mechanism.