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In electromagnetism, current density is the amount of charge per unit time that flows through a unit area of a chosen cross section. [1] The current density vector is defined as a vector whose magnitude is the electric current per cross-sectional area at a given point in space, its direction being that of the motion of the positive charges at this point.
The exchange current is the current at equilibrium, i.e. the rate at which oxidized and reduced species transfer electrons with the electrode. In other words, the exchange current density is the rate of reaction at the reversible potential (when the overpotential is zero by definition).
The Tafel equation describes the dependence of current for an electrolytic process to overpotential. The exchange current density is the current in the absence of net electrolysis and at zero overpotential. The exchange current can be thought of as a background current to which the net current observed at various overpotentials is normalized.
Continuous charge distribution. The volume charge density ρ is the amount of charge per unit volume (cube), surface charge density σ is amount per unit surface area (circle) with outward unit normal n̂, d is the dipole moment between two point charges, the volume density of these is the polarization density P.
The upper graph shows the current density as function of the overpotential η . The anodic and cathodic current densities are shown as j a and j c, respectively for α=α a =α c =0.5 and j 0 =1mAcm −2 (close to values for platinum and palladium). The lower graph shows the logarithmic plot for different values of α (Tafel plot).
The charge density appears in the continuity equation for electric current, and also in Maxwell's Equations. It is the principal source term of the electromagnetic field; when the charge distribution moves, this corresponds to a current density. The charge density of molecules impacts chemical and separation processes.
In the case where the electron/hole transport is limited by trap states in the form of exponential tails extending from the conduction/valence band edges, = (), the drift current density is given by the Mark-Helfrich equation, [10] = ((+)) (+ +) + + + where is the elementary charge, = / with being the thermal energy, is the effective ...
The hole mobility is defined by a similar equation: =. Both electron and hole mobilities are positive by definition. Usually, the electron drift velocity in a material is directly proportional to the electric field, which means that the electron mobility is a constant (independent of the electric field).