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The atom would then be pulled toward or away from the stronger magnetic field a specific amount, depending on the value of the valence electron's spin. When the spin of the electron is + + 1 / 2 the atom moves away from the stronger field, and when the spin is − + 1 / 2 the atom moves toward it. Thus the beam of silver atoms is ...
Spin is an intrinsic form of angular momentum carried by elementary particles, and thus by composite particles such as hadrons, atomic nuclei, and atoms. [1] [2]: 183–184 Spin is quantized, and accurate models for the interaction with spin require relativistic quantum mechanics or quantum field theory.
The spin magnetic moment of the electron is =, where is the spin (or intrinsic angular-momentum) vector, is the Bohr magneton, and = is the electron-spin g-factor. Here μ {\displaystyle {\boldsymbol {\mu }}} is a negative constant multiplied by the spin , so the spin magnetic moment is antiparallel to the spin.
Each is therefore an unpaired electron, but the total spin is zero and the multiplicity is 2S + 1 = 1 despite the two unpaired electrons. The multiplicity of the second excited state is therefore not equal to the number of its unpaired electrons plus one, and the rule which is usually true for ground states is invalid for this excited state.
The spin g-factor g s = 2 comes from the Dirac equation, a fundamental equation connecting the electron's spin with its electromagnetic properties. Reduction of the Dirac equation for an electron in a magnetic field to its non-relativistic limit yields the Schrödinger equation with a correction term, which takes account of the interaction of ...
The spin magnetic quantum number m s specifies the z-axis component of the spin angular momentum for a particle having spin quantum number s. For an electron, s is 1 ⁄ 2, and m s is either + 1 ⁄ 2 or − 1 ⁄ 2, often called "spin-up" and "spin-down", or α and β.
In quantum mechanics, a triplet state, or spin triplet, is the quantum state of an object such as an electron, atom, or molecule, having a quantum spin S = 1. It has three allowed values of the spin's projection along a given axis m S = −1, 0, or +1, giving the name "triplet".
Spin density is electron density applied to free radicals. It is defined as the total electron density of electrons of one spin minus the total electron density of the electrons of the other spin. One of the ways to measure it experimentally is by electron spin resonance, [14] neutron diffraction allows direct mapping of the spin density in 3D ...