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Oxygen (chemical symbol O) has three naturally occurring isotopes: 16 O, 17 O, and 18 O, where the 16, 17 and 18 refer to the atomic mass.The most abundant is 16 O, with a small percentage of 18 O and an even smaller percentage of 17 O. Oxygen isotope analysis considers only the ratio of 18 O to 16 O present in a sample.
Measurements of 18 O/ 16 O ratio are often used to interpret changes in paleoclimate. Oxygen in Earth's air is 99.759% 16 O, 0.037% 17 O and 0.204% 18 O. [13] Water molecules with a lighter isotope are slightly more likely to evaporate and less likely to fall as precipitation, [14] so Earth's freshwater and polar ice have slightly less (0.1981% ...
In ice cores, mainly Arctic and Antarctic, the ratio of 18 O to 16 O (known as δ 18 O) can be used to determine the temperature of precipitation through time.Assuming that atmospheric circulation and elevation has not changed significantly over the poles, the temperature of ice formation can be calculated as equilibrium fractionation between phases of water that is known for different ...
In geochemistry, paleoclimatology and paleoceanography δ 18 O or delta-O-18 is a measure of the deviation in ratio of stable isotopes oxygen-18 (18 O) and oxygen-16 (16 O). It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, and as an indicator of processes that show isotopic fractionation, like methanogenesis.
ISO TR 29922-2017 provides a definition for standard dry air which specifies an air molar mass of 28,965 46 ± 0,000 17 kg·kmol-1. [2] GPA 2145:2009 is published by the Gas Processors Association. It provides a molar mass for air of 28.9625 g/mol, and provides a composition for standard dry air as a footnote. [3]
Such regulations involve a number of different expressions of concentration. Some express the concentrations as ppmv and some express the concentrations as mg/m 3 , while others require adjusting or correcting the concentrations to reference conditions of moisture content, oxygen content or carbon dioxide content.
The δ values and absolute isotope ratios of common reference materials are summarized in Table 1 and described in more detail below. Alternative values for the absolute isotopic ratios of reference materials, differing only modestly from those in Table 1, are presented in Table 2.5 of Sharp (2007) [1] (a text freely available online), as well as Table 1 of the 1993 IAEA report on isotopic ...
Due to confusion over multiple water standards, the Commission on Isotopic Abundances and Atomic Weights recommended in 1994 that all future isotopic measurements of oxygen-18 (18 O) and deuterium (2 H) be reported relative to VSMOW, on a scale such that the δ 18 O of SLAP is −55.5‰ and the δ 2 H of SLAP is −428‰, relative to VSMOW.