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In China, early tin was extracted along the Yellow River in Erlitou and Shang times between 2500 and 1800 BC. By Han and later times, China imported its tin from what is today Yunnan province. This has remained China's main source of tin throughout history and into modern times. [49]
Tin mining began early in the Bronze Age, as bronze is a copper-tin alloy. Tin is a relatively rare element in the Earth's crust, with approximately 2 ppm (parts per million), compared to iron with 50,000 ppm.
Tin was first smelted in combination with copper around 3500 BC to produce bronze - and thus giving place to the Bronze Age (except in some places which did not experience a significant Bronze Age, passing directly from the Neolithic Stone Age to the Iron Age). [18]
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals, such as phosphorus, or metalloids, such as arsenic or silicon.
Bronze tiger inlaid with gold and silver, Han dynasty. Metallurgy in China has a long history, with the earliest metal objects in China dating back to around 3,000 BCE. The majority of early metal items found in China come from the North-Western Region (mainly Gansu and Qinghai, 青海).
Gold, silver and bronze or copper were the principal coinage metals of the ancient world, the medieval period and into the late modern period when the diversity of coinage metals increased. Coins are often made from more than one metal, either using alloys, coatings ( cladding / plating ) or bimetallic configurations.
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Most of the tin came from the Cornwall region of the island of Great Britain, transported by sea-borne Phoenician and Greek traders. Copper and bronze cannot be hardened by heat-treatment, they can only be hardened by cold working. To accomplish this, a piece of bronze is lightly hammered for a long period of time.