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In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction
The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change.
where K is the stability constant for the competition reaction. Thus, the value of the stability constant K A B {\displaystyle K_{AB}} may be derived from the experimentally determined values of K and K A C {\displaystyle K_{AC}} .
The binding constant, or affinity constant/association constant, is a special case of the equilibrium constant K, [1] and is the inverse of the dissociation constant. [2] It is associated with the binding and unbinding reaction of receptor (R) and ligand (L) molecules, which is formalized as: R + L ⇌ RL
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
From this plot, − Δ r H / R is the slope, and Δ r S / R is the intercept of the linear fit. By measuring the equilibrium constant, K eq, at different temperatures, the Van 't Hoff plot can be used to assess a reaction when temperature changes.
where K is a constant independent of initial composition, known as the equilibrium constant. The reaction proceeds in the forward direction (towards larger values of Q r) when Δ r G < 0 or in the reverse direction (towards smaller values of Q r) when Δ r G > 0. Eventually, as the reaction mixture reaches chemical equilibrium, the activities ...
(b) Constant pressure and temperature: heat =, where = + is the enthalpy of the system The magnitudes of the heat effects in these two conditions are different. In the first case the volume of the system is kept constant during the course of the measurement by carrying out the reaction in a closed and rigid container, and as there is no change ...