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It often occurs as the trihydrate K 3 [Fe(C 2 O 4) 3]·3H 2 O. Both are crystalline compounds, lime green in colour. [4] The compound is a salt consisting of ferrioxalate anions, [Fe(C 2 O 4) 3] 3−, and potassium cations K +. The anion is a transition metal oxalate complex consisting of an iron atom in the +3 oxidation state and three ...
Prussian blue or "ferric ferrocyanide", Fe 4 [Fe(CN) 6] 3, is an old and well-known iron-cyanide complex, extensively used as pigment and in several other applications. Its formation can be used as a simple wet chemistry test to distinguish between aqueous solutions of Fe 2+ and Fe 3+ as they react (respectively) with potassium ferricyanide and ...
Although nearly 100% sulfuric acid solutions can be made, the subsequent loss of SO 3 at the boiling point brings the concentration to 98.3% acid. The 98.3% grade, which is more stable in storage, is the usual form of what is described as "concentrated sulfuric acid".
The various crystalline forms of Fe 2 (SO 4) 3 (H 2 O) n are well-defined, often by X-ray crystallography. The nature of the aqueous solutions is often less certain, but aquo-hydroxo complexes such as [Fe(H 2 O) 6] 3+ and [Fe(H 2 O) 5 (OH)] 2+ are often assumed. [4] Regardless, all such solids and solutions feature ferric ions, each with five ...
All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H 2 O) 6] 2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas ...
Like other iron oxalates, ferrous oxalates feature octahedral Fe centers. The dihydrate FeC 2 O 4 (H 2 O) x is a coordination polymer, consisting of chains of oxalate-bridged ferrous centers, each with two aquo ligands. [3] When heated to 120 °C, the dihydrate dehydrates, and the anhydrous ferrous oxalate decomposes near 190 °C. [4]
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Greigite, Fe 3 S 4 (cubic) Pyrrhotite, Fe 1−x S (where x = 0 to 0.2) (monoclinic or hexagonal) Troilite, FeS, the endmember of pyrrhotite (hexagonal)