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Dipotassium phosphate (K 2 HPO 4) (also dipotassium hydrogen orthophosphate; potassium phosphate dibasic) is the inorganic compound with the formula K 2 HPO 4. (H 2 O) x (x = 0, 3, 6). Together with monopotassium phosphate (KH 2 PO 4. (H 2 O) x), it is often used as a fertilizer, food additive, and buffering agent. [1]
Monopotassium phosphate can exist in several polymorphs.At room temperature it forms paraelectric crystals with tetragonal symmetry. Upon cooling to −150 °C (−238 °F) it transforms to a ferroelectric phase of orthorhombic symmetry, and the transition temperature shifts up to −50 °C (−58 °F) when hydrogen is replaced by deuterium. [8]
Potassium phosphate is a generic term for the salts of potassium and phosphate ions including: [1] Monopotassium phosphate (KH 2 PO 4) (Molar mass approx: 136 g/mol) Dipotassium phosphate (K 2 HPO 4) (Molar mass approx: 174 g/mol) Tripotassium phosphate (K 3 PO 4) (Molar mass approx: 212.27 g/mol) As food additives, potassium phosphates have ...
This is a list of CAS numbers by chemical formulas and chemical compounds, indexed by formula.The CAS number is a unique number applied to a specific chemical by the Chemical Abstracts Service (CAS).This list complements alternative listings to be found at list of inorganic compounds and glossary of chemical formulae
The term phosphate is also used in organic chemistry for the functional groups that result when one or more of the hydrogens are replaced by bonds to other groups. These acids, together with their salts and esters , include some of the best-known compounds of phosphorus, of high importance in biochemistry , mineralogy , agriculture , pharmacy ...
The phosphate ion has a molar mass of 94.97 g/mol, and consists of a central phosphorus atom surrounded by four oxygen atoms in a tetrahedral arrangement. It is the conjugate base of the hydrogen phosphate ion H(PO 4) 2−, which in turn is the conjugate base of the dihydrogen phosphate ion H 2 (PO 4) −
The pKa of KHP is 5.4, so its pH buffering range would be 4.4 to 6.4; however, due to the presence of the second acidic group that bears the potassium ion, the first pKa also contributes to the buffering range well below pH 4.0, which is why KHP is a good choice for use as a reference standard for pH 4.00.
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