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The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, HSO − 4, which is in turn the conjugate base of H 2 SO 4, sulfuric acid. Organic sulfate esters , such as dimethyl sulfate , are covalent compounds and esters of sulfuric acid.
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4.Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
The concentration of hydrogen ions and pH are inversely proportional; in an aqueous solution, an increased concentration of hydrogen ions yields a low pH, and subsequently, an acidic product. By definition, an acid is an ion or molecule that can donate a proton, and when introduced to a solution it will react with water molecules (H 2 O) to ...
4, such that the total scale includes the effect of both protons (free hydrogen ions) and hydrogen sulfate ions: [H +] T = [H +] F + [HSO − 4] An alternative scale, the free scale, often denoted pH F, omits this consideration and focuses solely on [H +] F, in principle making it a simpler representation of hydrogen ion concentration.
The fluorosulfates or fluorosulfonates are a set of salts of fluorosulfuric acid with an ion formula SO 3 F −. The fluorosulfate anion can be treated as though it were a hydrogen sulfate anion with hydroxyl substituted by fluorine. [1] The fluorosulfate ion has a low propensity to form complexes with metal cations.
An alternative protocol uses a solution of iodate ion (for instance potassium iodate) to which an acidified solution (again with sulfuric acid) of sodium bisulfite is added. [3] In this protocol, iodide ion is generated by the following slow reaction between the iodate and bisulfite: IO − 3 + 3 HSO − 3 → I − + 3 HSO − 4
The reagent used can be any substance that gives S 2− ions in such solutions; most commonly used are hydrogen sulfide (at 0.2-0.3 M), thioacetamide (at 0.3-0.6 M), addition of hydrogen sulfide can often prove to be a lumbersome process and therefore sodium sulfide can also serve the purpose. The test with the sulfide ion must be conducted in ...
Fenton's reagent is a solution of hydrogen peroxide (H 2 O 2) and an iron catalyst (typically iron(II) sulfate, FeSO 4). [1] It is used to oxidize contaminants or waste water as part of an advanced oxidation process. Fenton's reagent can be used to destroy organic compounds such as trichloroethylene and tetrachloroethylene (perchloroethylene).