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The magnetic structure of α-hematite was the subject of considerable discussion and debate during the 1950s, as it appeared to be ferromagnetic with a Curie temperature of approximately 1,000 K (730 °C), but with an extremely small magnetic moment (0.002 Bohr magnetons). Adding to the surprise was a transition with a decrease in temperature ...
Magnetite has been important in understanding the conditions under which rocks form. Magnetite reacts with oxygen to produce hematite, and the mineral pair forms a buffer that can control how oxidizing its environment is (the oxygen fugacity). This buffer is known as the hematite-magnetite or HM buffer.
Iron minerals on the Earth's surface are typically richly oxidized, forming hematite, with Fe 3+ state, or in somewhat less oxidizing environments, magnetite, with a mixture of Fe 3+ and Fe 2+. Wüstite, in geochemistry, defines a redox buffer of oxidation within rocks at which point the rock is so reduced that Fe 3+, and thus hematite, is absent.
Maghemite (Fe 2 O 3, γ-Fe 2 O 3) is a member of the family of iron oxides.It has the same formula as hematite, but the same spinel ferrite structure as magnetite (Fe 3 O 4) and is also ferrimagnetic.
Iron(II,III) oxide, or black iron oxide, is the chemical compound with formula Fe 3 O 4.It occurs in nature as the mineral magnetite.It is one of a number of iron oxides, the others being iron(II) oxide (FeO), which is rare, and iron(III) oxide (Fe 2 O 3) which also occurs naturally as the mineral hematite.
Gangue minerals are typically some form of iron oxide mineral, classically hematite, but also magnetite within some other examples such as Ernest Henry and some Argentinian examples. This is typically associated with gangue sulfides of pyrite, with subordinate pyrrhotite and other base metal sulfides.
Corundum group minerals have a 2:3 ratio, and includes minerals such as corundum (Al 2 O 3), and hematite (Fe 2 O 3). Rutile group minerals have a ratio of 1:2; the eponymous species, rutile (TiO 2 ) is the chief ore of titanium ; other examples include cassiterite (SnO 2 ; ore of tin ), and pyrolusite (MnO 2 ; ore of manganese ).
The iron content of taconite is generally 30% to 35%, and the silica content generally around 45%. Iron in taconite is commonly present as magnetite, iron silicates, and iron-bearing carbonates, and locally martite (hematite) formed by oxidation of magnetite.
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