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A calorimeter is a device used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types.
A calorimeter constant (denoted C cal) is a constant that quantifies the heat capacity of a calorimeter. [ 1 ] [ 2 ] It may be calculated by applying a known amount of heat to the calorimeter and measuring the calorimeter's corresponding change in temperature .
The specific heat capacity of a substance is typically determined according to the definition; namely, by measuring the heat capacity of a sample of the substance, usually with a calorimeter, and dividing by the sample's mass.
Table of specific heat capacities at 25 °C (298 K) unless otherwise noted. [citation needed] Notable minima and maxima are shown in maroon. Substance Phase Isobaric mass heat capacity c P J⋅g −1 ⋅K −1 Molar heat capacity, C P,m and C V,m J⋅mol −1 ⋅K −1 Isobaric volumetric heat capacity C P,v J⋅cm −3 ⋅K −1 Isochoric ...
The heat capacity at constant volume is assumed to be independent of temperature. Heat is measured by the principle of calorimetry. = =, where ΔU is change in internal energy, ΔT is change in temperature and C V is the heat capacity at constant volume.
The first adiabatic differential scanning calorimeter that could be used in biochemistry was developed by P. L. Privalov and D. R. Monaselidze in 1964 at Institute of Physics in Tbilisi, Georgia. [4] The term DSC was coined to describe this instrument, which measures energy directly and allows precise measurements of heat capacity. [5]
Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. [1] The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property.
The heat liberated or absorbed by the process is determined from the difference between the initial electrical power and the electrical power required at the time of measurement. While power compensation calorimetry requires less preparation than heat flow calorimetry, it faces similar limitations.