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  2. Methyl butyrate - Wikipedia

    en.wikipedia.org/wiki/Methyl_butyrate

    Methyl butyrate, also known under the systematic name methyl butanoate, is the methyl ester of butyric acid. Like most esters, it has a fruity odor, in this case resembling apples or pineapples. [2] At room temperature, it is a colorless liquid with low solubility in water, upon which it floats to form an oily layer.

  3. Butyrate fermentation - Wikipedia

    en.wikipedia.org/wiki/Butyrate_fermentation

    Subsequently, ATP is produced in the last step of the fermentation. Three molecules of ATP are produced for each glucose molecule, a relatively high yield. The balanced equation for this fermentation is C 6 H 12 O 6 → C 4 H 8 O 2 + 2CO 2 + 2H 2. Other pathways to butyrate include succinate reduction and crotonate disproportionation.

  4. Butyric acid - Wikipedia

    en.wikipedia.org/wiki/Butyric_acid

    Subsequently, ATP is produced in the last step of the fermentation. Three molecules of ATP are produced for each glucose molecule, a relatively high yield. The balanced equation for this fermentation is C 6 H 12 O 6 → C 4 H 8 O 2 + 2CO 2 + 2H 2. Other pathways to butyrate include succinate reduction and crotonate disproportionation.

  5. Butyrate kinase - Wikipedia

    en.wikipedia.org/wiki/Butyrate_kinase

    In enzymology, a butyrate kinase (EC 2.7.2.7) is an enzyme that catalyzes the chemical reaction ADP + butyryl-phosphate ⇌ {\displaystyle \rightleftharpoons } ATP + butyrate Thus, the two substrates of this enzyme are ADP and butyryl-phosphate , whereas its two products are ATP and butyrate .

  6. Migratory insertion - Wikipedia

    en.wikipedia.org/wiki/Migratory_insertion

    Steps in alkene polymerization. Step i involves binding of the monomer to the metal and step ii involves the migratory insertion step. These steps, which alternate from one side of the metal center to the other, are repeated many times for each polymer chain. The box represents a vacant (or extremely labile) coordination site.

  7. Butyryl-CoA - Wikipedia

    en.wikipedia.org/wiki/Butyryl-CoA

    The red arrow is the succinate fermentation pathway; the blue arrow is the ethanol/acetyl-CoA fermentation pathway, also known as ABE fermentation. Butyryl-CoA is reduced from crotonyl-CoA catalyzing by butyryl-CoA dehydrogenase, where two NADH molecules donate four electrons, with two of them reducing ferredoxin ([2Fe-2S] cluster) and the ...

  8. Monsanto process - Wikipedia

    en.wikipedia.org/wiki/Monsanto_process

    The first organometallic step is the oxidative addition of methyl iodide to cis-[Rh(CO) 2 I 2] − to form the hexacoordinate species [(CH 3)Rh(CO) 2 I 3] −. This anion rapidly transforms, via the migration of a methyl group to an adjacent carbonyl ligand, affording the pentacoordinate acetyl complex [(CH 3 CO)Rh(CO)I 3] −.

  9. Butanol fuel - Wikipedia

    en.wikipedia.org/wiki/Butanol_fuel

    Many organisms have the capacity to produce butanol utilizing an acetyl-CoA dependent pathway. The main problem with this pathway is the first reaction involving the condensation of two acetyl-CoA molecules to acetoacetyl-CoA. This reaction is thermodynamically unfavorable due to the positive Gibbs free energy associated with it (dG = 6.8 kcal ...