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Homogeneous reactions are chemical reactions in which the reactants and products are in the same phase, while heterogeneous reactions have reactants in two or more phases. Reactions that take place on the surface of a catalyst of a different phase are also heterogeneous. A reaction between two gases or two miscible liquids is homogeneous.
In chemistry, homogeneous catalysis is catalysis where the catalyst is in same phase as reactants, principally by a soluble catalyst in a solution. In contrast, heterogeneous catalysis describes processes where the catalysts and substrate are in distinct phases, typically solid and gas, respectively. [ 1 ]
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to ... Acids are an example of a homogeneous catalyst, ...
In homogeneous photocatalysis, the reactants and the photocatalysts exist in the same phase. The process by which the atmosphere self-cleans and removes large organic compounds is a gas phase homogenous photocatalysis reaction. [ 26 ]
In chemistry, a phase-transfer catalyst or PTC is a catalyst that facilitates the transition of a reactant from one phase into another phase where reaction occurs. Phase-transfer catalysis is a special form of catalysis and can act through homogeneous catalysis or heterogeneous catalysis methods depending on the catalyst used.
Homogeneous electrocatalysts, which are soluble, assist in transferring electrons between the electrode and reactants, and/or facilitate an intermediate chemical transformation described by an overall half reaction. [2] Major challenges in electrocatalysts focus on fuel cells. [3] [4]
In organic chemistry, a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the more general coupling reactions. Often cross-coupling reactions require metal catalysts. One important reaction type is this:
As stated above, Tolman's rule, even for reactions that proceed via 2e − steps, is incorrect because many reactions involve configurations of fewer than 16 e −. Many examples of homogeneous catalysis involving organometallic complexes involve shuttling of complexes between 16 and 18 electron configurations.
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