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The equation was postulated by Schrödinger based on a postulate of Louis de Broglie that all matter has an associated matter wave. The equation predicted bound states of the atom in agreement with experimental observations. [4]: II:268 The Schrödinger equation is not the only way to study quantum mechanical systems and make predictions.
The Schrödinger equation determines how wave functions evolve over time, and a wave function behaves qualitatively like other waves, such as water waves or waves on a string, because the Schrödinger equation is mathematically a type of wave equation. This explains the name "wave function", and gives rise to wave–particle duality.
The failure of classical mechanics applied to molecular, atomic, and nuclear systems and smaller induced the need for a new mechanics: quantum mechanics.The mathematical formulation was led by De Broglie, Bohr, Schrödinger, Pauli, and Heisenberg, and others, around the mid-1920s, and at that time was analogous to that of classical mechanics.
The stationary nuclei enter the problem only as generators of an electric potential in which the electrons move in a quantum mechanical way. Within this framework the molecular Hamiltonian has been simplified to the so-called clamped nucleus Hamiltonian, also called electronic Hamiltonian, that acts only on functions of the electronic coordinates.
The Schrödinger equation applies to the new Hamiltonian. Solutions to the untransformed and transformed equations are also related by U {\displaystyle U} . Specifically, if the wave function ψ ( t ) {\displaystyle \psi (t)} satisfies the original equation, then U ψ ( t ) {\displaystyle U\psi (t)} will satisfy the new equation.
Several phenomena have the same behavior as quantum tunnelling. Two examples are evanescent wave coupling [49] (the application of Maxwell's wave-equation to light) and the application of the non-dispersive wave-equation from acoustics applied to "waves on strings". [citation needed] These effects are modeled similarly to the rectangular ...
Source: [1] The potential splits the space in two parts (x < 0 and x > 0).In each of these parts the potential is zero, and the Schrödinger equation reduces to =; this is a linear differential equation with constant coefficients, whose solutions are linear combinations of e ikx and e −ikx, where the wave number k is related to the energy by =.
A wave function is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the wave function together with the rules for the system's evolution in time exhausts all that can be predicted about the system's behavior.