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The polyamic acid precursor to Kapton is mixed with an acrylate cross linker and photoinitiator that can form a gel when exposed to ultraviolet light during 3D printing. Subsequent heating of the 3D printed part up to 400 °C removes the sacrificial crosslinks and imidizes the part forming Kapton with a 3D printed geometry.
Although typically "doping" conductive polymers involves oxidizing or reducing the material, conductive organic polymers associated with a protic solvent may also be "self-doped." Undoped conjugated polymers are semiconductors or insulators. In such compounds, the energy gap can be > 2 eV, which is too great for thermally activated conduction.
Thermally processed material is usually totally amorphous, [7] and as a result is highly transparent to visible light, with better light transmission than many kinds of glass. Polycarbonate has a glass transition temperature of about 147 °C (297 °F), [ 8 ] so it softens gradually above this point and flows above about 155 °C (311 °F). [ 9 ]
A desktop FFF printer made by Stratasys. Fused deposition modeling was developed by S. Scott Crump, co-founder of Stratasys, in 1988. [6] [7] With the 2009 expiration of the patent on this technology, [8] people could use this type of printing without paying Stratasys for the right to do so, opening up commercial, DIY, and open-source 3D printer applications.
3D printing, or additive manufacturing, is the construction of a three-dimensional object from a CAD model or a digital 3D model. [1] [2] [3] It can be done in a variety of processes in which material is deposited, joined or solidified under computer control, [4] with the material being added together (such as plastics, liquids or powder grains being fused), typically layer by layer.
Substantial effort has been focused on 3D printing parameter optimization by many methods [15] including with the Taguchi methods to enable ASA to be used for high-end applications. [ 16 ] ASA with compounds of silver , rendering its surface antimicrobial by the silver's oligodynamic effect , was introduced to the market in 2008.
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