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This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
Other than using infinite basis sets, two methods exist to eliminate the BSSE. In the chemical Hamiltonian approach (CHA), [4] [5] basis set mixing is prevented a priori, by replacing the conventional Hamiltonian with one in which all the projector-containing terms that would allow mixing have
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A full history of the Green Book's various editions is provided in the historical introduction to the third edition. The second edition and the third edition (second printing) of the Green Book have both been made available online as PDF files; the PDF version of the third edition is fully searchable. The four-page concise summary is also ...
Any non-linear differentiable function, (,), of two variables, and , can be expanded as + +. If we take the variance on both sides and use the formula [11] for the variance of a linear combination of variables (+) = + + (,), then we obtain | | + | | +, where is the standard deviation of the function , is the standard deviation of , is the standard deviation of and = is the ...
The most fundamental concept in chemistry is the law of conservation of mass, which states that there is no detectable change in the quantity of matter during an ordinary chemical reaction. Modern physics shows that it is actually energy that is conserved, and that energy and mass are related; a concept which becomes important in nuclear chemistry.
Major philosophical questions arise as soon as one attempts to define chemistry and what it studies. Atoms and molecules are often assumed to be the fundamental units of chemical theory, [3] but traditional descriptions of molecular structure and chemical bonding fail to account for the properties of many substances, including metals and metal complexes [4] and aromaticity.
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