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A hydrogen bond (H-bond), is a specific type of interaction that involves dipole–dipole attraction between a partially positive hydrogen atom and a highly electronegative, partially negative oxygen, nitrogen, sulfur, or fluorine atom (not covalently bound to said hydrogen atom). It is not a covalent bond, but instead is classified as a strong ...
Figure 1. Example of salt bridge between amino acids glutamic acid and lysine demonstrating electrostatic interaction and hydrogen bonding. In chemistry, a salt bridge is a combination of two non-covalent interactions: hydrogen bonding and ionic bonding (Figure 1).
The bond then results from electrostatic attraction between the positive and negatively charged ions. Ionic bonds may be seen as extreme examples of polarization in covalent bonds. Often, such bonds have no particular orientation in space, since they result from equal electrostatic attraction of each ion to all ions around them.
What is more commonly observed (see figure to the right) is either a staggered stacking (parallel displaced) or pi-teeing (perpendicular T-shaped) interaction both of which are electrostatic attractive [2] [3] For example, the most commonly observed interactions between aromatic rings of amino acid residues in proteins is a staggered stacked ...
A simple example for a prototypical electron-donor-acceptor complexes is nitroaniline. [3] 1,3,5-Trinitrobenzene and related polynitrated aromatic compounds, being electron-deficient, form charge-transfer complexes with many arenes. Such complexes form upon crystallization, but often dissociate in solution to the components.
Naturally, the question of the distance at which these electrostatic interactions become important arises. This can be discussed using the Bjerrum length. The Bjerrum length is the distance at which the electrostatic interaction between two charges is comparable to the thermal energy, . The distance is given by eq. 2:
Both electrostatic mapping and molecular orbital explanation for chalcogen bonding result in a predicted directionality for the bonding interaction. In a hydrogen or halogen bond, the electrophilic region/σ* orbital are located opposite the σ bond, forming a single σ-hole. Optimal hydrogen or halogen bonds thus are linear in geometry.
PSS is a 'strong' polyelectrolyte (fully charged in solution), whereas PAA is 'weak' (partially charged). Polyelectrolytes are polymers whose repeating units bear an electrolyte group. Polycations and polyanions are polyelectrolytes. These groups dissociate in aqueous solutions (water), making the polymers charged.