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The Rüchardt experiment, [1] [2] [3] invented by Eduard Rüchardt, is a famous experiment in thermodynamics, which determines the ratio of the molar heat capacities of a gas, i.e. the ratio of (heat capacity at constant pressure) and (heat capacity at constant volume) and is denoted by (gamma, for ideal gas) or (kappa, isentropic exponent, for real gas).
Gay-Lussac used the formula acquired from ΔV/V = αΔT to define the rate of expansion α for gases. For air, he found a relative expansion ΔV/V = 37.50% and obtained a value of α = 37.50%/100 °C = 1/266.66 °C which indicated that the value of absolute zero was approximately 266.66 °C below 0 °C. [ 12 ]
In fact, it is (loosely speaking) the simplest differential operator which has these symmetries. This can be taken as a significant (and purely mathematical) justification of the use of the Laplacian and of the heat equation in modeling any physical phenomena which are homogeneous and isotropic, of which heat diffusion is a principal example.
The heat flow can be modelled by analogy to an electrical circuit where heat flow is represented by current, temperatures are represented by voltages, heat sources are represented by constant current sources, absolute thermal resistances are represented by resistors and thermal capacitances by capacitors.
Eddy currents in conductors of non-zero resistivity generate heat as well as electromagnetic forces. The heat can be used for induction heating. The electromagnetic forces can be used for levitation, creating movement, or to give a strong braking effect. Eddy currents can also have undesirable effects, for instance power loss in transformers.
Although the Drude model was fairly successful in describing the electron motion within metals, it has some erroneous aspects: it predicts the Hall coefficient with the wrong sign compared to experimental measurements, the assumed additional electronic heat capacity to the lattice heat capacity, namely per electron at elevated temperatures, is also inconsistent with experimental values, since ...
In 1841 and 1842, subsequent experiments showed that the amount of heat generated was proportional to the chemical energy used in the voltaic pile that generated the template. This led Joule to reject the caloric theory (at that time the dominant theory) in favor of the mechanical theory of heat (according to which heat is another form of energy ).
The author then explains how heat is defined or measured by calorimetry, in terms of heat capacity, specific heat capacity, molar heat capacity, and temperature. [ 42 ] A respected text disregards the Carathéodory's exclusion of mention of heat from the statement of the first law for closed systems, and admits heat calorimetrically defined ...