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Lanthanide metals react exothermically with hydrogen to form LnH 2, dihydrides. [1] With the exception of Eu and Yb, which resemble the Ba and Ca hydrides (non-conducting, transparent salt-like compounds),they form black pyrophoric, conducting compounds [6] where the metal sub-lattice is face centred cubic and the H atoms occupy tetrahedral sites. [1]
The lanthanide (/ ˈ l æ n θ ə n aɪ d /) or lanthanoid (/ ˈ l æ n θ ə n ɔɪ d /) series of chemical elements [a] comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals.
Atmospheric electricity utilization for the chemical reaction in which water is separated into oxygen and hydrogen. (Image via: Vion, US patent 28793. June 1860.) Electrolyser front with electrical panel in foreground. Electrolysis of water is the decomposition of water (H 2 O) into oxygen (O 2) and hydrogen (H 2): [2] Water electrolysis ship ...
A separatory funnel used for liquid–liquid extraction, as evident by the two immiscible liquids.. Liquid–liquid extraction, also known as solvent extraction and partitioning, is a method to separate compounds or metal complexes, based on their relative solubilities in two different immiscible liquids, usually water (polar) and an organic solvent (non-polar).
In chemistry, thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. [1] The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled.
A separation process is a method that converts a mixture or a solution of chemical substances into two or more distinct product mixtures, [1] a scientific process of separating two or more substances in order to obtain purity. At least one product mixture from the separation is enriched in one or more of the source mixture's constituents.
The process of water-splitting is a highly endothermic process (ΔH > 0). Water splitting occurs naturally in photosynthesis when the energy of four photons is absorbed and converted into chemical energy through a complex biochemical pathway (Dolai's or Kok's S-state diagrams). [3] O–H bond homolysis in water requires energy of 6.5 - 6.9 eV ...
This can be used to separate different metals such as the lanthanides. With ammonium nitrate in the aqueous phase, thorium nitrate prefers the organic liquid, and the lanthanides stay with the water. [3] Thorium nitrate dissolved in water lowers it freezing point. The maximum freezing point depression is −37 °C with a concentration of 2.9 ...