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The methyl ester of ricinoleic acid, obtained from castor bean oil, is the main commercial precursor to enanthic acid. It is pyrolyzed to the methyl ester of 10-undecenoic acid and heptanal, which is then air-oxidized to the carboxylic acid. Approximately 20,000 tons were consumed in Europe and US in 1980.
An ester of carboxylic acid.R stands for any group (organic or inorganic) and R′ stands for organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (−R).
Structure of the allyl group. In organic chemistry, an allyl group is a substituent with the structural formula −CH 2 −HC=CH 2.It consists of a methylene bridge (−CH 2 −) attached to a vinyl group (−CH=CH 2).
The formation of heptanal in the fractional distillation of castor oil [3] was already described in 1878. The large-scale production is based on the pyrolytic cleavage of ricinoleic acid [4] (Arkema method) and on the hydroformylation of 1-hexene with rhodium 2-ethylhexanoate as a catalyst upon addition of some 2-ethylhexanoic acid (Oxea method): [2] [5]
Ethyl heptanoate is the ester resulting from the condensation of heptanoic acid and ethanol. It is used in the flavor industry because of its odor that is similar to grape. It is used in the flavor industry because of its odor that is similar to grape.
Stearyl heptanoate, the ester of stearyl alcohol and heptanoic acid (enanthic acid), is found in most cosmetic eyeliners. Stearyl alcohol has also found application as an evaporation suppressing monolayer when applied to the surface of water. [2] Stearyl alcohol is prepared from stearic acid or certain fats by the process of catalytic ...
Methyl pentanoate, commonly known as methyl valerate, is the methyl ester of pentanoic acid (valeric acid) with a fruity odor. Methyl pentanoate is commonly used in fragrances, beauty care, soap, laundry detergents at levels of 0.1–1%. In a very pure form (greater than 99.5%) it is used as a plasticizer in the manufacture of plastics.
Heptanone may refer to the following ketones with seven carbon atoms the formula C 7 H 14 O: . 2-Heptanone (Methyl amyl ketone) . 5-Methyl-2-hexanone (Methyl isoamyl ketone); 4-Methyl-2-hexanone (Methyl 2-methylbutyl ketone)