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Thermal physics, generally speaking, is the study of the statistical nature of physical systems from an energetic perspective. Starting with the basics of heat and temperature, thermal physics analyzes the first law of thermodynamics and second law of thermodynamics from the statistical perspective, in terms of the number of microstates corresponding to a given macrostate.
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation.
But in another sense, heat is transferred in different ranks, as expressed by Arnold Sommerfeld's dictum "Thermodynamics investigates the conditions that govern the transformation of heat into work. It teaches us to recognize temperature as the measure of the work-value of heat. Heat of higher temperature is richer, is capable of doing more work.
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
Historically, the term 'free energy' has been used for either quantity. In physics, free energy most often refers to the Helmholtz free energy, denoted by A (or F), while in chemistry, free energy most often refers to the Gibbs free energy. The values of the two free energies are usually quite similar and the intended free energy function is ...
The heat capacity depends on how the external variables of the system are changed when the heat is supplied. If the only external variable of the system is the volume, then we can write: d S = ( ∂ S ∂ T ) V d T + ( ∂ S ∂ V ) T d V {\displaystyle dS=\left({\frac {\partial S}{\partial T}}\right)_{V}dT+\left({\frac {\partial S}{\partial V ...
The author then explains how heat is defined or measured by calorimetry, in terms of heat capacity, specific heat capacity, molar heat capacity, and temperature. [ 42 ] A respected text disregards the Carathéodory's exclusion of mention of heat from the statement of the first law for closed systems, and admits heat calorimetrically defined ...
Joule's apparatus for measuring the mechanical equivalent of heat in which the "work" of the falling weight is converted into the "heat" of agitation in the water. Benjamin Thompson, Count Rumford, had observed the frictional heat generated by boring cannon at the arsenal in Munich, Bavaria, circa 1797. Rumford immersed a cannon barrel in water ...