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The axis of rotation is tilted by the magic angle θ m with respect to the direction of B 0. In solid-state NMR spectroscopy , magic-angle spinning (MAS) is a technique routinely used to produce better resolution NMR spectra.
The GF method, sometimes referred to as FG method, is a classical mechanical method introduced by Edgar Bright Wilson to obtain certain internal coordinates for a vibrating semi-rigid molecule, the so-called normal coordinates Q k.
Rotational frequency, also known as rotational speed or rate of rotation (symbols ν, lowercase Greek nu, and also n), is the frequency of rotation of an object around an axis. Its SI unit is the reciprocal seconds (s −1 ); other common units of measurement include the hertz (Hz), cycles per second (cps), and revolutions per minute (rpm).
Quantifying mass transfer allows for design and manufacture of separation process equipment that can meet specified requirements, estimate what will happen in real life situations (chemical spill), etc. Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of ...
Radius of gyration (in polymer science)(, unit: nm or SI unit: m): For a macromolecule composed of mass elements, of masses , =1,2,…,, located at fixed distances from the centre of mass, the radius of gyration is the square-root of the mass average of over all mass elements, i.e.,
The trivial case of the angular momentum of a body in an orbit is given by = where is the mass of the orbiting object, is the orbit's frequency and is the orbit's radius.. The angular momentum of a uniform rigid sphere rotating around its axis, instead, is given by = where is the sphere's mass, is the frequency of rotation and is the sphere's radius.
As a detailed example, ammonia has a moment of inertia I C = 4.4128 × 10 −47 kg m 2 about the 3-fold rotation axis, and moments I A = I B = 2.8059 × 10 −47 kg m 2 about any axis perpendicular to the C 3 axis. Since the unique moment of inertia is larger than the other two, the molecule is an oblate symmetric top. [8] Asymmetric tops ...
The Levich equation is written as: = where I L is the Levich current (A), n is the number of moles of electrons transferred in the half reaction (number), F is the Faraday constant (C/mol), A is the electrode area (cm 2), D is the diffusion coefficient (see Fick's law of diffusion) (cm 2 /s), ω is the angular rotation rate of the electrode (rad/s), ν is the kinematic viscosity (cm 2 /s), C ...