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Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications. [2]
Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.
Sodium sulfate is a typical electrostatically bonded ionic sulfate. The existence of free sulfate ions in solution is indicated by the easy formation of insoluble sulfates when these solutions are treated with Ba 2+ or Pb 2+ salts: Na 2 SO 4 + BaCl 2 → 2 NaCl + BaSO 4. Sodium sulfate is unreactive toward most oxidizing or reducing agents.
It is no longer commonly used, having been superseded by the cheaper sodium analog. Chloramine, NH 2 Cl. This chemical is commonly handled as a dilute aqueous solution. It is used as an alternative to chlorine and sodium hypochlorite for disinfection of drinking water and swimming pools. Chloramine-T, or tosylchloramide sodium salt, [(H 3 C)(C ...
How about mentioning sodium thiosulfate's use for removing chlorine from water, important for those keeping fish in aquariums (and how this works). Gary 11:49, 9 April 2006 (UTC) [ reply ] Safety of sodium thiosulfate in swimming pools; signs & symptoms of overuse
For instance, benzalkonium chloride (a quaternary-type cationic surfactant) may be determined in cleaners and algaecides for swimming pools and spas by titrating with a standard solution of sodium dodecyl sulfate. Alternatively, anionic surfactants such as sodium lauryl sulfate can be titrated with cetyl pyridinium chloride. Fig. 18.
I feel the author has confused sodium sulfate with sodium bisulfate. This also contradicts an earlier portion of the article which says (correctly) that sodium sulfate is a neutral salt. Finally I have looked at the msds of many "pH down" products for swimming pools. Most of which are >90% sodium bisulfate with a small percentage of sodium sulfate.
The triiodide ion solution is then titrated against standard thiosulfate solution to give iodide again using starch indicator: I − 3 + 2 e − ⇌ 3 I − (E 0 = +0.54 V) Together with reduction potential of thiosulfate: [1] S 4 O 2− 6 + 2 e − ⇌ 2 S 2 O 2− 3 (E 0 = +0.08 V) The overall reaction is thus: I − 3 + 2 S 2 O 2− 3 → S ...
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