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Hypochlorous acid is an inorganic compound with the chemical formula Cl O H, also written as HClO, HOCl, or ClHO. [2] [3] Its structure is H−O−Cl.It is an acid that forms when chlorine dissolves in water, and itself partially dissociates, forming a hypochlorite anion, ClO −.
For example, acetic acid is a weak acid which has a = 1.75 x 10 −5. Its conjugate base is the acetate ion with K b = 10 −14 /K a = 5.7 x 10 −10 (from the relationship K a × K b = 10 −14), which certainly does not correspond to a strong base. The conjugate of a weak acid is often a weak base and vice versa.
For example, aqueous perchloric acid (HClO 4), aqueous hydrochloric acid (HCl) and aqueous nitric acid (HNO 3) are all completely ionized, and are all equally strong acids. [3] Similarly, when ammonia is the solvent, the strongest acid is ammonium (NH 4 +), thus HCl and a super acid exert the same acidifying effect. The same argument applies to ...
Chemical bonds are described as having different strengths: there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force, and hydrogen bonding.
Hypohalous acids tend to be weak acids, and they typically get weaker as the halogen progresses further down the periodic table. Hypochlorous acid has a pK a of 7.53. [5] The pK a values of hypobromous acid is higher (meaning that it is an even weaker acid), [6] at 8.65. The pK a of hypoiodous acid is even higher, at 10.6. [7]
For example, pK a for HClO is 7.2, for HClO 2 is 2.0, for HClO 3 is −1 and HClO 4 is a strong acid (pK a ≪ 0). [7] The increased acidity on adding an oxo group is due to stabilization of the conjugate base by delocalization of its negative charge over an additional oxygen atom. [47]
The higher the percentage, the stronger the electrolyte. Thus, even if a substance is not very soluble, but does dissociate completely into ions, the substance is defined as a strong electrolyte. Similar logic applies to a weak electrolyte. Strong acids and bases are good examples, such as HCl and H 2 SO 4. These will all exist as ions in an ...
On the other hand, if a chemical is a weak acid its conjugate base will not necessarily be strong. Consider that ethanoate, the conjugate base of ethanoic acid, has a base splitting constant (Kb) of about 5.6 × 10 −10, making it a weak base. In order for a species to have a strong conjugate base it has to be a very weak acid, like water.