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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The black tarnish commonly seen on silver arises from its sensitivity to sulphur containing gases such as hydrogen sulfide: 2 Ag + H 2 S + 1 / 2 O 2 → Ag 2 S + H 2 O. Rayner-Canham [ 4 ] contends that, "silver is so much more chemically-reactive and has such a different chemistry, that it should not be considered as a 'noble metal'."
Electroless deposition is an important process in the electronic industry for metallization of substrates. Other metallization of substrates also include physical vapor deposition (PVD), chemical vapor deposition (CVD), and electroplating which produce thin metal films but require high temperature, vacuum, and a power source respectively. [20]
Marcel Pourbaix (16 September 1904 – 28 September 1998) was a Belgian chemist and pianist. [citation needed] He performed his most well known research at the University of Brussels, studying corrosion. [1] His biggest achievement is the derivation of potential-pH, better known as “Pourbaix Diagrams”.
Platinum black (Pt black) is a fine powder of platinum with good catalytic properties. The name of platinum black is due to its black color. The name of platinum black is due to its black color. It is used in many ways; as a thin film electrode, a fuel cell membrane catalyst, or as a catalytic ignition of flammable gases for "self-lighting' gas ...
Not sure how to resolve this, the horizontal pH scale on the iron Pourbaix diagram is incorrect, counting: "0 2 4 6 8 10 11 14". I just fixed that typo in the figure's X axis. Olawlor ( talk ) 06:32, 6 April 2019 (UTC) [ reply ]
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Similar to Pourbaix diagrams for the speciation of redox species as a function of the redox potential and the pH, ionic partition diagrams indicate in which phase an acid or a base is predominantly present in a biphasic system as a function of the Galvani potential difference between the two phases and the pH of the aqueous solution.