Search results
Results from the WOW.Com Content Network
Optical activity is reciprocal, i.e. it is the same for opposite directions of wave propagation through an optically active medium, for example, clockwise polarization rotation from the point of view of an observer. In case of optically active isotropic media, the rotation is the same for any direction of wave propagation.
In organic chemistry, an electrocyclic reaction can either be classified as conrotatory or disrotatory based on the rotation at each end of the molecule. In conrotatory mode, both atomic orbitals of the end groups turn in the same direction (such as both atomic orbitals rotating clockwise or counter-clockwise). In disrotatory mode, the atomic ...
Absolute configuration uses a set of rules to describe the relative positions of each bond around the chiral center atom. The most common labeling method uses the descriptors R or S and is based on the Cahn–Ingold–Prelog priority rules. R and S refer to rectus and sinister, Latin for right and left, respectively.
However, in navigation, compass headings increase clockwise around the compass face, starting with 0° at the top of the compass (the northerly direction), with 90° to the right (east). A circle defined parametrically in a positive Cartesian plane by the equations x = cos t and y = sin t is traced counterclockwise as the angle t increases in ...
A 180° rotation (middle) followed by a positive 90° rotation (left) is equivalent to a single negative 90° (positive 270°) rotation (right). Each of these figures depicts the result of a rotation relative to an upright starting position (bottom left) and includes the matrix representation of the permutation applied by the rotation (center ...
Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation (α) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ([α]) for the enantiopure compound is known.
A sphere rotating (spinning) about an axis. Rotation or rotational motion is the circular movement of an object around a central line, known as an axis of rotation.A plane figure can rotate in either a clockwise or counterclockwise sense around a perpendicular axis intersecting anywhere inside or outside the figure at a center of rotation.
The angle θ and axis unit vector e define a rotation, concisely represented by the rotation vector θe.. In mathematics, the axis–angle representation parameterizes a rotation in a three-dimensional Euclidean space by two quantities: a unit vector e indicating the direction of an axis of rotation, and an angle of rotation θ describing the magnitude and sense (e.g., clockwise) of the ...