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In chemistry, a sulfonyl halide consists of a sulfonyl (>S(=O) 2) group singly bonded to a halogen atom. They have the general formula RSO 2 X, where X is a halogen. The stability of sulfonyl halides decreases in the order fluorides > chlorides > bromides > iodides, all four types being well known. The sulfonyl chlorides and fluorides are of ...
On heating, zinc nitrate undergoes thermal decomposition to form zinc oxide, nitrogen dioxide and oxygen: 2 Zn(NO 3) 2 → 2 ZnO + 4 NO 2 + 1 O 2. Aqueous zinc nitrate contains aquo complexes [Zn(H 2 O) 6] 2+ and [Zn(H 2 O) 4] 2+. [3] and, thus, this reaction may be better written as the reaction of the aquated ion with hydroxide through ...
Sulfonyl groups can be written as having the general formula R−S(=O) 2 −R′, where there are two double bonds between the sulfur and oxygen. [1]: 53 [2] Sulfonyl groups can be reduced to the sulfide with diisobutylaluminium hydride (DIBALH). Lithium aluminium hydride (LiAlH 4) reduces some but not all sulfones to sulfides. [1]: 1851
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO 2 F 2. It is an easily condensed gas and has properties more similar to sulfur hexafluoride than sulfuryl chloride , being resistant to hydrolysis even up to 150 °C. [ 3 ]
Sodium fluoride: yellow is fluorine, purple is sodium. They are isoelectronic, but fluorine is bigger because its nuclear charge is lower. The alkali metals form monofluorides. All are soluble and have the sodium chloride (rock salt) structure, [47] Because the fluoride anion is basic, many alkali metal fluorides form bifluorides with the ...
Zinc fluoride is an inorganic chemical compound with the chemical formula Zn F 2. It is encountered as the anhydrous form and also as the tetrahydrate, ZnF 2 ·4H 2 O (rhombohedral crystal structure). [2] It has a high melting point and has the rutile structure containing 6 coordinate zinc, which suggests appreciable ionic character in its ...
Trimethylsilyl enol ethers react with NfF in the presence of a substoichiometric fluoride source at 0 °C to ambient temperature to give alkenyl nonaflates in moderate to good yields. Dried tetra-n-butylammonium fluoride was the preferred fluoride source in one study, [6] but CsF has been used in difficult cases with excellent results. [7]