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The reduction of O 2 by metal catalysts is a key half-reaction in fuel cells. Metal-catalyzed oxidations with O 2 proceed via the intermediacy of dioxygen complexes, although the actual oxidants are often oxo derivatives. The reversible binding of O 2 to metal complexes has been used as a means to purify oxygen from air, but cryogenic ...
A basic oxide, also called a base anhydride (meaning "base without water"), is usually formed in the reaction of oxygen with metals, especially alkali (group 1) and alkaline earth (group 2) metals. Both of these groups form ionic oxides that dissolve in water to form basic solutions of the corresponding metal hydroxide: Alkali metals (Group 1)
The reactive oxygen ion superoxide is particularly important as the product of the one-electron reduction of dioxygen O 2, which occurs widely in nature. [2] Molecular oxygen (dioxygen) is a diradical containing two unpaired electrons, and superoxide results from the addition of an electron which fills one of the two degenerate molecular ...
2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron, will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt, such as iron(II) sulfate: Fe (s) + H 2 SO 4 (l) → FeSO 4 (aq) + H 2 (g) There is some ambiguity at the borderlines ...
A transition metal oxo complex is a coordination complex containing an oxo ligand. Formally O 2–, an oxo ligand can be bound to one or more metal centers, i.e. it can exist as a terminal or (most commonly) as bridging ligands. Oxo ligands stabilize high oxidation states of a metal. [1]
Reaction with halogens. Ca + Cl 2 → CaCl 2. Anhydrous calcium chloride is a hygroscopic substance that is used as a desiccant. Exposed to air, it will absorb water vapour from the air, forming a solution. This property is known as deliquescence. Reaction with oxygen. Ca + 1/2O 2 → CaO Mg + 1/2O 2 → MgO. Reaction with sulfur. Ca + 1/8S 8 ...
Complexes of the transition metals are usually generated simply by treating the appropriate metal complex with SO 2. The adducts are often weak. In some cases, SO 2 displaces other ligands. [3] A large number of labile O-bonded SO 2 complexes arise from the oxidation of a suspension of the metals in liquid SO 2, an excellent solvent. [2]
Group 1 and group 2 metals in compounds have OS = +1 and +2, respectively. Hydrogen has OS = +1 but adopts −1 when bonded as a hydride to metals or metalloids. Oxygen in compounds has OS = −2 but only when not bonded to oxygen (e.g. in peroxides) or fluorine.