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Major changes in bicycle form have often been initiated or accompanied by advances in drivetrain systems. Several early drivetrains used straight-cut gears that meshed directly with each other outside of the hub. [1] [2] Some bicycles have used a double-sided rear wheel, with different-sized sprockets on each side. To change gears, the rider ...
The Suzuki reaction or Suzuki coupling is an organic reaction that uses a palladium complex catalyst to cross-couple a boronic acid to an organohalide. [1] [2] [3] It was first published in 1979 by Akira Suzuki, and he shared the 2010 Nobel Prize in Chemistry with Richard F. Heck and Ei-ichi Negishi for their contribution to the discovery and development of noble metal catalysis in organic ...
The mechanism of protodeboronation was initially investigated by Kuivila in the 1960s, long before the discovery of the Suzuki reaction and the popularisation of boronic acids. Their studies focused on the protodeboronation of some substituted aromatic boronic acids in aqueous conditions, and they reported the presence of two distinct ...
The Miyaura borylation has shown to work for: Alkyl halides, [ 2 ] aryl halides, [ 1 ] [ 3 ] [ 4 ] aryl halides using tetrahydroxydiboron , [ 5 ] aryl halides using bis-boronic acid, [ 6 ] aryl triflates , [ 7 ] aryl mesylates , [ 8 ] vinyl halides, [ 9 ] vinyl halides of α,β-unsaturated carbonyl compounds, [ 10 ] and vinyl triflates.
Converting a non-electric bicycle to its electric equivalent can be complicated but numerous 'replace a wheel' solutions are now available on the market. [44] An Electric Pusher Trailer is an e-bike design which incorporates a motor and battery into a trailer that pushes any bicycle. One such trailer is the two-wheeled Ridekick.
[2] At the Stanley Cycle Show in 1896 in London, England, bicycle manufacturer Humber exhibited an electric tandem bicycle. Powered by a bank of storage batteries, the motor was placed in front of the rear wheel. Speed control was by a resistance placed across the handlebars. This electric bicycle was mainly intended for racetrack use. [3]
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