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δ 13 C sample is the delta-value of the organism for 13 C composition; δ 13 C atm is the delta-value of atmospheric CO 2, which is = -7.8‰ the discrimination due to diffusion a = 4.4‰ the carboxylation discrimination b = 30‰ c a is the partial pressure of CO 2 in the external atmosphere, and; c i is the partial pressure of CO 2 in the ...
Carbon-13 has a non-zero spin quantum number of 1 / 2 , and hence allows the structure of carbon-containing substances to be investigated using carbon-13 nuclear magnetic resonance. The carbon-13 urea breath test is a safe and highly accurate diagnostic tool to detect the presence of Helicobacter pylori infection in the stomach. [4]
The standard established for carbon-13 work was the Pee Dee Belemnite (PDB) and was based on a Cretaceous marine fossil, Belemnitella americana, which was from the Peedee Formation in South Carolina. This material had an anomalously high 13 C: 12 C ratio (0.0112372 [4]), and was established as δ 13 C value of zero.
One of these, the standard for normalizing δ 13 C values, is Pee Dee Belemnite (PDB), a fossil which has a 13 C / 12 C ratio of 1.12372%. [3] δ 13 C for some sample is then calculated by dividing the amount of 13 C by 1.12372% and then subtracting 1 and multiplying by 1000 to give a value in "per mil". [4]
Similarly, marine fish contain more 13 C than freshwater fish, with values approximating the C 4 and C 3 plants respectively. The ratio of carbon-13 and carbon-12 isotopes in these types of plants is as follows: [11] C 4 plants: −16‰ to −10‰ CAM plants: −20‰ to −10‰ C 3 plants: −33‰ to −24‰
The δ values and absolute isotope ratios of common reference materials are summarized in Table 1 and described in more detail below. Alternative values for the absolute isotopic ratios of reference materials, differing only modestly from those in Table 1, are presented in Table 2.5 of Sharp (2007) [1] (a text freely available online), as well as Table 1 of the 1993 IAEA report on isotopic ...
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A carbon-13 label was used to determine the mechanism in the 1,2- to 1,3-didehydrobenzene conversion of the phenyl substituted aryne precursor 1 to acenaphthylene. [3]An isotopic tracer, (also "isotopic marker" or "isotopic label"), is used in chemistry and biochemistry to help understand chemical reactions and interactions.