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The vapor pressure affects the solute shown by Raoult's Law while the free energy change and chemical potential are shown by Gibbs free energy. Most solutes remain in the liquid phase and do not enter the gas phase, except at very high temperatures. In terms of vapor pressure, a liquid boils when its vapor pressure equals the surrounding pressure.
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
In structural geology and diagenesis, pressure solution or pressure dissolution is a deformation mechanism that involves the dissolution of minerals at grain-to-grain contacts into an aqueous pore fluid in areas of relatively high stress and either deposition in regions of relatively low stress within the same rock or their complete removal ...
In simple words, we can say that the partial pressure of a gas in vapour phase is directly proportional to the mole fraction of a gas in solution. An example where Henry's law is at play is the depth-dependent dissolution of oxygen and nitrogen in the blood of underwater divers that changes during decompression, going to decompression sickness.
Pressure in water and air. Pascal's law applies for fluids. Pascal's principle is defined as: A change in pressure at any point in an enclosed incompressible fluid at rest is transmitted equally and undiminished to all points in all directions throughout the fluid, and the force due to the pressure acts at right angles to the enclosing walls.
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
An ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. [1] The enthalpy of mixing is zero [2] as is the volume change on mixing by definition; the closer to zero the enthalpy of mixing is, the more "ideal" the behavior of the solution becomes.
The change in pressure over distance dx is dp and flow velocity v = dx / dt . Apply Newton's second law of motion (force = mass × acceleration) and recognizing that the effective force on the parcel of fluid is −A dp. If the pressure decreases along the length of the pipe, dp is negative but the force resulting in flow is positive ...