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The principal sources of rare-earth elements are the minerals bastnäsite (RCO 3 F, where R is a mixture of rare-earth elements), monazite (XPO 4, where X is a mixture of rare-earth elements and sometimes thorium), and loparite ((Ce,Na,Ca)(Ti,Nb)O 3), and the lateritic ion-adsorption clays.
A piece of yttrium. Yttrium is difficult to separate from other rare-earth elements. Rare-earth elements (REEs) come mainly from four sources: [58] Carbonate and fluoride containing ores such as the LREE bastnäsite ((Ce, La, etc.)(CO 3)F) contain on average 0.1% [15] [56] yttrium compared to the 99.9% for the 16 other REEs. [56]
It is the sixth-most abundant rare-earth element and fourth-most abundant lanthanide, making up 9.1 parts per million of the Earth's crust, an abundance similar to that of boron. In 1841, Swedish chemist Carl Gustav Mosander extracted a rare-earth oxide residue he called didymium from a residue he called "lanthana", in turn separated from ...
Neodymium is a fairly common element in the Earth's crust for being a rare-earth metal. Most rare-earth metals are less abundant. Neodymium is classified as a lithophile under the Goldschmidt classification, meaning that it is generally found combined with oxygen. Although it belongs to the rare-earth metals, neodymium is not rare at all. Its ...
In the periodic table, it appears between the elements europium to its left and terbium to its right, and above the actinide curium. It is a silvery-white, malleable, ductile rare-earth element. Its 64 electrons are arranged in the configuration of [Xe]4f 7 5d 1 6s 2, of which the ten 4f, 5d, and 6s electrons are valence.
In the periodic table published by Dmitri Mendeleev in 1869, thorium and the rare-earth elements were placed outside the main body of the table, at the end of each vertical period after the alkaline earth metals. This reflected the belief at that time that thorium and the rare-earth metals were divalent.
The term rare-earth element or rare-earth metal is often used to include the stable group 3 elements Sc, Y, and Lu in addition to the 4f elements. [8] All lanthanide elements form trivalent cations, Ln 3+, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum (La) to lutetium (Lu).
The most efficient separation routine for terbium salt from the rare-earth salt solution is ion exchange. In this process, rare-earth ions are sorbed onto suitable ion-exchange resin by exchange with hydrogen, ammonium or cupric ions present in the resin. The rare earth ions are then selectively washed out by suitable complexing agents. As with ...