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The enthalpy of vaporization is a function of the pressure and temperature at which the transformation (vaporization or evaporation) takes place. The enthalpy of vaporization is often quoted for the normal boiling temperature of the substance. Although tabulated values are usually corrected to 298 K, that correction is often smaller than the ...
For a liquid–gas transition, is the specific latent heat (or specific enthalpy) of vaporization; for a solid–gas transition, is the specific latent heat of sublimation. If the latent heat is known, then knowledge of one point on the coexistence curve , for instance (1 bar, 373 K) for water, determines the rest of the curve.
ΔHvap is the molar enthalpy of vaporization of the solvent. Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ebullioscopy means "boiling measurement" in Latin. This is related to cryoscopy, which determines the same value from the cryoscopic constant (of freezing point ...
Water (H2O) is a polar inorganic compound that is at room temperature a tasteless and odorless liquid, which is nearly colorless apart from an inherent hint of blue. It is by far the most studied chemical compound [19] and is described as the "universal solvent " [20] and the "solvent of life". [21]
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...
The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine [fr] (1825–1897). [1]
Entropy of vaporization. In thermodynamics, the entropy of vaporization is the increase in entropy upon vaporization of a liquid. This is always positive, since the degree of disorder increases in the transition from a liquid in a relatively small volume to a vapor or gas occupying a much larger space. At standard pressure = 1 bar, the ...
A closely related property of a substance is the heat capacity per mole of atoms, or atom-molar heat capacity, in which the heat capacity of the sample is divided by the number of moles of atoms instead of moles of molecules. So, for example, the atom-molar heat capacity of water is 1/3 of its molar heat capacity, namely 25.3 J⋅K −1 ⋅mol ...