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Triplet chlorophyll is a potent photosensitiser of molecular oxygen forming singlet oxygen which can cause oxidative damage to the pigments, lipids and proteins of the photosynthetic thylakoid membrane. To counter this problem, one photoprotective mechanism is so-called non-photochemical quenching (NPQ), which relies upon the conversion and ...
The excited, triplet state photosensitizer then reacts with a substrate molecule which is not molecular oxygen to both form a product and reform the photosensitizer. Type I photosensitized reactions result in the photosensitizer being quenched by a different chemical substrate than molecular oxygen.
This small difference makes chlorophyll b absorb light with wavelengths between 400 and 500 nm more efficiently. Carotenoids are long linear organic molecules that have alternating single and double bonds along their length. Such molecules are called polyenes. Two examples of carotenoids are lycopene and β-carotene. These molecules also absorb ...
The light-harvesting complex (or antenna complex; LH or LHC) is an array of protein and chlorophyll molecules embedded in the thylakoid membrane of plants and cyanobacteria, which transfer light energy to one chlorophyll a molecule at the reaction center of a photosystem. The antenna pigments are predominantly chlorophyll b, xanthophylls, and ...
Examples of photosensitizers or light harvesting materials that are used to target cancer cells are semiconductor nanoparticles, [44] ruthenium complexes, [46] and nanocomplexes. [47] Photosensitizers can be used for the formation of singlet oxygen upon photoinduction and this plays an important role in photodynamic therapy and this capability ...
In living organisms, photoinhibited PSII centres are continuously repaired via degradation and synthesis of the D1 protein of the photosynthetic reaction center of PSII. Photoinhibition is also used in a wider sense, as dynamic photoinhibition, to describe all reactions that decrease the efficiency of photosynthesis when plants are exposed to ...
This is a cyclic process in which electrons are removed from an excited chlorophyll molecule (bacteriochlorophyll; P870), passed through an electron transport chain to a proton pump (cytochrome bc 1 complex; similar to the chloroplastic one), and then returned to the chlorophyll molecule. The result is a proton gradient that is used to make ATP ...
The cofactors can be pigments (like chlorophyll, pheophytin, carotenoids), quinones, or iron-sulfur clusters. [7] Each photosystem has two main subunits: an antenna complex (a light harvesting complex or LHC) and a reaction center. The antenna complex is where light is captured, while the reaction center is where this light energy is ...