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  2. Photosensitizer - Wikipedia

    en.wikipedia.org/wiki/Photosensitizer

    The excited, triplet state photosensitizer then reacts with a substrate molecule which is not molecular oxygen to both form a product and reform the photosensitizer. Type I photosensitized reactions result in the photosensitizer being quenched by a different chemical substrate than molecular oxygen.

  3. Non-photochemical quenching - Wikipedia

    en.wikipedia.org/wiki/Non-photochemical_quenching

    Triplet chlorophyll is a potent photosensitiser of molecular oxygen forming singlet oxygen which can cause oxidative damage to the pigments, lipids and proteins of the photosynthetic thylakoid membrane. To counter this problem, one photoprotective mechanism is so-called non-photochemical quenching (NPQ), which relies upon the conversion and ...

  4. Light harvesting materials - Wikipedia

    en.wikipedia.org/wiki/Light_harvesting_materials

    The light harvesting complex in purple bacteria is multifunctional; at high light intensities, the light harvesting complex typically switches into a quenched state through a conformational change of the PPC, and at low light intensities, the light harvesting complex typically reverts to an unquenched state. [11]

  5. Photoredox catalysis - Wikipedia

    en.wikipedia.org/wiki/Photoredox_catalysis

    The long-lived triplet excited state accessible by photoexcitation is both a more potent reducing agent and a more potent oxidizing agent than the ground state of the catalyst. Since sensitizer is coordinatively saturated, electron transfer must occur by an outer sphere process, where the electron tunnels between the catalyst and the substrate.

  6. Light-dependent reactions - Wikipedia

    en.wikipedia.org/wiki/Light-dependent_reactions

    This is a cyclic process in which electrons are removed from an excited chlorophyll molecule (bacteriochlorophyll; P870), passed through an electron transport chain to a proton pump (cytochrome bc 1 complex; similar to the chloroplastic one), and then returned to the chlorophyll molecule. The result is a proton gradient that is used to make ATP ...

  7. Hexazinone - Wikipedia

    en.wikipedia.org/wiki/Hexazinone

    Hexazinone is an organic compound that is used as a broad spectrum herbicide. It is a colorless solid. It exhibits some solubility in water but is highly soluble in most organic solvents except alkanes. A member of the triazine class herbicides, it is manufactured by DuPont and sold under the trade name Velpar. [1]

  8. Di-π-methane rearrangement - Wikipedia

    en.wikipedia.org/wiki/Di-π-methane_rearrangement

    The barrelene rearrangement is more complex than the Mariano and Pratt examples since there are two sp 3-hybridized carbons. Each bridgehead carbon has three (ethylenic) π bonds, and any two can undergo the di‑π-methane rearrangement. Moreover, unlike the acyclic Mariano and Pratt dienes, the barrelene reaction requires a triplet excited state.

  9. Triplet state - Wikipedia

    en.wikipedia.org/wiki/Triplet_state

    Examples of atoms in singlet, doublet, and triplet states. In quantum mechanics, a triplet state, or spin triplet, is the quantum state of an object such as an electron, atom, or molecule, having a quantum spin S = 1. It has three allowed values of the spin's projection along a given axis m S = −1, 0, or +1, giving the name "triplet".

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